Bio-inspired polymers (peptoids)
“Sequence Modulates Polypeptoid Hydration Water Structure and Dynamics.” Sally Jiao, Daniela M. Rivera Mirabal, Audra J. DeStefano, Rachel A. Segalman, Songi Han, and M. Scott Shell. Biomacromolecules 2022, Article ASAP. DOI: 10.1021/acs.biomac.1c01687
“Effects of Amphiphilic Polypeptoid Side Chains on Polymer Surface Chemistry and Hydrophilicity.” Mikayla E. Barry, Pinar Aydogan Gokturk, Audra J. DeStefano, Amanda K. Leonardi, Christopher K. Ober, Ethan J. Crumlin, and Rachel A. Segalman. ACS Applied Materials & Interfaces 2022, 14 (5), 7340-7349. DOI: 10.1021/acsami.1c22683
“Where Biology and Traditional Polymers Meet: The Potential of Associating Sequence-Defined Polymers for Materials Science.” Audra J. DeStefano, Rachel A. Segalman, and Emily C. Davidson. JACS Au 2021, 1 (10), 1556-1571. DOI: 10.1021/jacsau.1c00297
“Tuning the Double Gyroid Phase Window in Block Copolymers via Polymer Chain Conformation Near the Interface.” Beihang Yu, Ruipeng Li, and Rachel A. Segalman. Macromolecules 2021, 54 (12), 5388-5396. DOI: 10.1021/acs.macromol.1c00048
“Quantifying Polypeptoid Conformational Landscapes through Integrated Experiment and Simulation.” Sally Jiao, Audra DeStefano, Jacob I. Monroe, Mikayla Barry, Nicholas Sherck, Thomas Casey, Rachel A. Segalman, Songi Han, and M. Scott Shell. Macromolecules 2021, 54 (11), 5011-5021. DOI: 10.1021/acs.macromol.1c00550
“Insensitivity of Sterically Defined Helical Chain Conformations to Solvent Quality in Dilute Solution.” B. Yu, S. P. O. Danielsen, K. Yang, R. Ho, L. M. Walker, and R. A. Segalman. ACS Macro Lett. 2020, 9, 6, 849–854. DOI: 10.1021/acsmacrolett.0c00293
“Monomer Sequence Effects on Interfacial Width and Mixing in Self-Assembled Diblock Copolymers,” A. L. Patterson, B. Yu, S. P. O. Danielsen, E. C. Davidson, G. H. Fredrickson, and R. A. Segalman. Macromolecules 2020, 53, 9, 3262–3272. DOI: 10.1021/acs.macromol.9b02426
“Effects of Helical Chain Shape on Lamellae-Forming Block Copolymer Self-Assembly,” B. Yu, S. P. O. Danielsen, A. L. Patterson, E. C. Davidson, and R. A. Segalman. Macromolecules, 2019, Advance article.
DOI: 10.1021/acs.macromol.9b00211
“The Role of Hydrogen Bonding in Peptoid-Based Marine Antifouling Coatings,” M. E. Barry, E. C. Davidson, C. Zhang, A. L. Patterson, B. Yu, A. K. Leonardi, N. Duzen, K. Malaviya, J. L. Clarke, J. A. Finlay, A. S. Clare, Z. Chen, C. K. Ober, R. A. Segalman. Macromolecules, 2019, 52, 3, 1287–1295. DOI: 10.1021/acs.macromol.8b02390
“Sequence Effects on Block Copolymer Self-Assembly through Tuning Chain Conformation and Segregation Strength Utilizing Sequence-Defined Polypeptoids,” A. L. Patterson, S. P. O. Danielsen, B. Yu, E. C. Davidson, G. H. Fredrickson, R. A. Segalman. Macromolecules, 2019, 52, 3, 1277–1286. DOI: 10.1021/acs.macromol.8b02298
"Impact of Helical Chain Shape in Sequence-Defined Polymers on Polypeptoid Block Copolymer Self-Assembly," E. C. Davidson, A. Rosales, A. L. Patterson, B. Yu, R. Zuckermann, R. A. Segalman. Macromolecules, 2018, 51 (5), pp 2089–2098. DOI: 10.1021/acs.macromol.8b00055
"Oligopeptide-Modified Hydrophobic and Hydrophilic Polymers as Antifouling Coatings," D. R. Calabrese, B. M. Wenning, H. Buss, J. A. Finlay, A. S. Clare, D. Fischer, R. A. Segalman, C. K. Ober. Green Materials, 2017, 5, 1, 1–42. DOI: 10.1680/jgrma.17.00006
"Role of Backbone Chemistry and Monomer Sequence in Amphiphilic Oligopeptide- and Oligopeptoid-Functionalized PDMS- and PEO-Based Block Copolymers for Marine Antifouling and Fouling Release Coatings," A. L. Patterson, B. Wenning, G. Rizis, D. R. Calabrese, J. A. Finlay, S. C. Franco, R. N. Zuckermann, A. S. Clare, E. J. Kramer, C. K. Ober, R. A. Segalman. Macromolecules, 2017, 50, 7, 2656–2667. DOI: 10.1021/acs.macromol.6b02505
"Surface Structure and Hydration of Sequence-Specific Amphiphilic Polypeptoids for Antifouling/Fouling Release Applications," C. Leng, H.G. Buss, R.A. Segalman, Z. Chen, Langmuir, 2015, 31(34), 9306-9311. DOI: 10.1021/acs.langmuir.5b01440
"Sequence of Hydrophobic and Hydrophilic Residues in Amphiphilic Polymer Coatings Affects Surface Structure and Marine Antifouling/Fouling Release Properties," W.van Zoelen, H. Buss, N.C. Ellebracht, N. Lynd, D. Fischer, J. Finlay, S. Hill, M.E. Callow, J.A. Callow, E. Kramer, R.N. Zuckermann, R.A. Segalman,Macro Letters, 2014, 3 (4), 364-368.
"Polypeptoids: a model system to study the effect of monomer sequence on polymer properties and self-assembly," A.M. Rosales, R.A. Segalman, R.N. Zuckermann, Soft Matter, 2013, 9, 8400-8414.
"Persistence length of polyelectrolytes with precisely located charges," H.K. Murnen, A.M. Rosales, A.V. Dorynin, R.N. Zuckermann, R.A. Segalman, Soft Matter, 2013, 9, 90-98.
"Tunable Surface Properties from Sequence Specific Polypeptoid-Polystyrene Block Copolymer Thin Films," W. van Zoelen, R.N. Zuckermann, R.A. Segalman, Macromolecules, 2012, 45(17), 7072-7082.
"Tunable Phase Behavior of Polystyrene-Polypeptoid Block Copolymers," A.M. Rosales, B.L. McCulloch, R.N. Zuckermann, R.A. Segalman, Macromolecules, 2012, 45(15), 6027-6035.
"Impact of Hydrophobic Sequence Patterning on the Coil-to-Globule Transition of Protein-like Polymers," H.K. Murnen, A.R. Khokhlov, P.G. Khalatur, R.A. Segalman, R.N. Zuckermann, Macromolecules, 2012, 45(12), 5229-5236.
"Determination of the Persistence Length of Helical and Non-Helical Polypeptoids in Solution," A.M. Rosales, H.K. Murnen, S.R. Kline, R.N. Zuckermann, R.A. Segalman, Soft Matter, 2012, 8, 3673-3680.
"Hierarchical Self-Assembly of a Biomimetic Diblock Copolypeptoid into Homochiral Superhelices," H.K. Murnen, A.M. Rosales, J.N. Jaworski, R.A. Segalman, R.N. Zuckermann, J. Am. Chem. Soc., 2010, 132 (45), 16112-16119.
"Control of Crystallization and Melting Behavior in Sequence Specific Polypeptoids," A.M. Rosales, H.K. Murnen, R.N. Zuckerman, Macromolecules, 2010, 43 (13), 5627-5636.